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The unsaturated resin polymerization inhibitor MTBHQ (2-tert-butylhydroquinone) plays an important role in resin synthesis and other synthetic reactions. The following is a detailed analysis of its principle of action and effects:Effect Remarkable polymerization inhibition effect: MTBHQ is a kind of high efficient polymerization inhibitor for unsaturated resin. Under normal storage conditions, the general addition amount is only two ten-thousandths of the total amount of resin, and it can play a good effect of polymerization inhibition.
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Animal fats undergo a series of reactions such as the aggregation of fats, the production and transmission of free radicals, and so on at high temperatures. At the same time, animal fats lack natural antioxidants, so it is necessary to add effective antioxidants to maintain an appropriate shelf life. Chen Yongquan et al. measured the changes in peroxide value of samples added with different antioxidants in lard while studying the antioxidant properties of TBHQ.
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Possible reaction pathways of 2,5-di-tert-butyl-hydroquinone (2,5-DTBHQ).Valgimigli et al. proposed a mechanism wherein semiquinone (2) reacts with molecular oxygen to produce 2,5-di-tert-butyl-1,4-benzoquinone (2,5-DTBBQ) and hydroperoxyl radical (HOO∙). The semiquinone (2) terminates a second propagation chain via either hydrogen abstraction (Reaction II) or addition reaction (Reaction IV) and these reaction pathways play a very critical role in the inhibition process.
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Product Parameters2-tert-butylhydroquinone as a food additive, TBHQ has been used in the United States and other more than 20 countries, China in 1992 was approved for use in oil and fat-containing foods, thousands of fish products, biscuits, quick-cooking noodles, canned fat-containing foods, cured meat products and so on.
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There are two types of antioxidants, one is chemical synthesized and the other is natural antioxidants. Chemical synthesis, such as BHT, BHQ, TBHQ, ethoxyquinoline, PE, etc., these are considered to be called chemical synthesis of antioxidants, these antioxidants have been banned in Europe, that in China and the United States, is the amount of additive per kilogram can not be greater than 0.2, these chemical synthesis of antioxidants, it is true that there is now some controversy, but the antioxidant effect is relatively good.
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White to light gray crystal or crystalline powder, with unique odor, melting point 126.5~128.5℃, boiling 300℃, slightly soluble in water (25℃, <1%), easily soluble in ethanol (120%), acetone (190%), ethyl acetate (100%), insoluble in toluene, and soluble in animal and vegetable oils. MTBHQ is specially used as polymer inhibitor, heat and mild stabilizer and industrial antioxidant.
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White to light gray crystal or crystalline powder, with special odor, melting point 126.5~128.5℃, boiling point 300℃, slightly soluble in water (25℃, <1%), easily soluble in ethanol (120%), acetone (190%), ethyl acetate (100%), insoluble in toluene, and soluble in animal and vegetable oils. MTBHQ is mainly used as polymer inhibitor, heat and light stabilizer and industrial antioxidant.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-02-Tertiary butyl dihydroquinone, also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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Hydroquinone Uses:In medicine, hydroquinone is mainly used in the treatment of pigmented skin diseases, such as chloasma and freckles, etc.
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When citric acid is combined with antioxidants, the higher the content of these impurities in the oil, the more obvious the synergistic effect.
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TBHQ has good oil solubility and thermal stability, and does not change in color after heating.They are only suitable for high water content oil and fat foods such as biscuits, instant noodles, artificial milk oil, and mayonnaise. When the oil contains a large amount of metal ions and oxygen, the addition of antioxidants can inhibit the formation of peroxides.Oxidized fish oil is harmful to human health, so it is important to prevent oxidation and improve the stability of fish oil.
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Product ParametersTert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.It is better to mix it with 0010.02% citric acid.This product cannot be mixed with PG (Propyl Gallate) for use.
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution.
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Heat the oil directly to 35-60C, add TBHQ in the required proportion, vigorously stir for 10-15 minutes to dissolve it, and then continue stirring (without vigorously stirring to prevent excessive air from entering) for about 20 minutes to ensure uniform distribution of TBHQ.The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution.
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When the oil contains a large amount of metal ions and oxygen, the addition of antioxidants can inhibit the formation of peroxides. When citric acid is combined with antioxidants, the higher the content of these impurities in the oil, the more obvious the synergistic effect. TBHQ has good oil solubility and thermal stability, and does not change in color after heating. It can be added before and after the deodorization process of oil.
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This may be due to TBHQ being more prone to volatilization under high temperature conditions and losing its effectiveness, and under certain conditions, TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions.
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Product ParametersTBHQ is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ ﹤ 5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of oil and fat deterioration in food.How to use the productSeed methodFirst dissolve TBHQ in a small amount of oil (or 95% alcohol solution), formulated as 5% ~ 10% of TBHQ oil (or alcohol solution), then directly or by the dosage added to the fat or
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Polymerization inhibitor TBHQ, is a white or slightly reddish-brown crystalline powder with a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in organic solvents such as ethanol, ethyl acetate, ether and so on.1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-02.Product CharacteristicsAntimicrobial effect: Polymerisation inhibitor TBHQ can effectively inhibit the growth of bacteria and moulds.Vegetable oil, animal fat, chewing gum, soup, seasoning, vitamins, grain food, nuts, essence, sausage, animal feed, grain food pac
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Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0 TBHQ has been used in more than 20 countries, such as the United States, and was approved to be used in oil and fat-containing foods, fish products, biscuits, quick-cooking noodles, canned fat-containing foods, cured meat products in China in 1992.
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Product Parameters：Lard antioxidant TBHQ is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ ﹤ 5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of oil and fat deterioration in food.Product Applications：At present, the most commonly used antioxidants in fats and oils and their products are BHA, BHT, PG, TBHQ and tocopherol.
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution. Then, directly or with a measuring device, it is added to the fat or oil and stirred evenly.The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.
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Product ParametersSunflower oil antioxidant TBHQ, i.e. TBHQ, is a white or slightly reddish-brown crystalline powder with a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in ethanol, ethyl acetate, ether and other organic solvents.How to use the productPumping methodSeed method of preparation of TBHQ concentrated solution, through the stainless steel quantitative pump in accordance with the prescribed ratio of injection needs to be stabilized with a fixed flow rate, flow rate of fat or oil in the pipeline.
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